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Thiol (reduced) glutathione and disulfide (oxidized) glutathione often act as actuators of molecular nano-switches that activate, regulate or inhibit the activity of enzymes as a response to the presence of different levels of reactive species, such as ROS and electrophilic organic metabolites

In vitro studies with human hepatocytes showed that phenytoin and phenobarbital inhibit acetaminophen glucuronidation, suggesting that other pathways of the drug metabolism, like oxidation to toxic NAPQI, may be potentiated [17,18]