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The ligands are the thiolate-containing amino acids such as cysteine [16], the di- and tri-(pseudo)peptides belonging to the biochemical pathway of glutathione, the oligomeric glutathione correlates in the plant kingdom known as phytochelatins and some thiols of pharmacological or other practical utility, such as N- acetyl-cysteine (NAC)

The pathway branches from glucose metabolism alongside glycolysis, running its own chemistry to produce NADPH and biosynthetic five-carbon sugars

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Specific microbial taxa, such as secondary bile acid-producing bacteria and reproductive tract-associated Lactobacillus spp ., are known to regulate IL-22 expression 187,214