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These structural features are relevant for laboratory interpretation because they reduce some variables that complicate work with cyclic or disulfide-containing peptides, such as incorrect disulfide pairing, oxidative folding state, or multiple disulfide-linked isomers

This distinction is required on the labels of research chemicals, and is what exempts them from regulation under parts 100-740 in Title 21 of the Code of Federal Regulations (21CFR)