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However, in situations involving physical stress, trauma, illness, or intense training, glutamine synthesis may not meet the bodys demand

L., Martorana, U., Cataldo, P., Brancato, G

These differences as well as alterations in conserved amino acids known or predicted to contribute to a functional scaffold site (Gln/Glu in helix 2 and Arg/Thr in the loop) 13 might be the reason why GSSG is not bound in a way that stable glutathionylation at low GSSG/GSH ratios is favoured