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The contribution of GSTs in the reduction of cellular hydroperoxides remains poorly described but it might be important because these are almost the only GSH-dependent peroxidases, most thiol peroxidases being dependent on GRXs or TRXs, including GPXLs ( Isomerase Activity Some GSTs, in particular from the Zeta class, catalyze the GSH-dependent isomerisation of specific metabolites, such as the cis-trans isomerisation of maleylacetoacetate into fumarylacetoacetate occurring during the penultimate step of tyrosine catabolism in eukaryotes ( Non-enzymatic Binding and Intracellular Transport In addition to their catalytic function, GSTs also serve as non-enzymatic carrier proteins or ligandins ( Zea mays GSTU1 is able to catalyze the conjugation of GSH on protoporphyrinogen IX and harderoporphyrinogen ( Petunia hybrida, A

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